ملخص المقال

The synthesis of new unsymmetrically benzene-fused bis (tetrathiafulvalene) has been carried out by a cross-coupling reaction of the respective 4,5-dialkyl-1,3-dithiole-2-selenone 6–9 with 2-(4-(p-nitrophenyl)-1,3-dithiole-2-ylidene)-1,3,5,7-tetrathia-s-indacene-6-one 5 prepared by olefination of 4-(p-nitrophenyl)-1,3-dithiole-2-selenone 3 and 1,3,5,7-tetrathia-s-indacene-2,6-dione 4. The conversion of the nitro moiety 10a–d to amino 11a–d then dibenzylamine 12a–d groups respectively used reduction and alkylation methods. The electron donor ability of these new compounds has been measured by cyclic voltammetry (CV) technique. Charge transfer complexes with tetracyanoquino-dimethane (TCNQ) were prepared by chemical redox reactions. The complexes have been proven to give conducting materials.

Keywords: conductivity; redox potentials; organic materials; tetrathiafulvalenes

معلومات

Item Type:	Journal
Divisions:	» مخبر النظم الإيكولوجية الأرضية والمائية » كلية العلوم و التكنولوجيا
ePrint ID:	203
Date Deposited:	2014-12-14
Further Information:	Google Scholar
URI:	https://www.univ-soukahras.dz/ar/publication/article/203

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