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A new unsymmetrical tetrathiafulvalenes (TTF) containing nitrophenyl or aminophenyl rings were prepared by using a cross-coupling method of the respective 4,5-dialkyl-1,3-dithiole-2-one 1a-e with 4-(p-nitrophenyl)-1,3- dithiole-2-thione 2. The conversion of the nitro moiety 3a-e to amino groups’ 4a-e used reduction reaction. The reducing power of each new precursor was determined by cyclic voltammetry. Charge transfer complexes of the donors with tetracyanoquino-dimethane (TCNQ) were prepared and characterized. The electrical conductivity of these materials was measured and discussed.

Keywords: tetrathiafulvalenes; electrochemistry; redox potentials; organic materials; conductivity

Item Type	Journal
Divisions	» Laboratory for Terrestrial and Aquatic Ecosystems » Faculty of Science and Technology
ePrint ID	205
Date Deposited	2014-12-14
Further Information	Google Scholar
URI	https://univ-soukahras.dz/en/publication/article/205

@article{uniusa205,
    title={Synthesis and properties of new metal complexes involving unsymmetrical tetrathiafulvalene},
    author={Tahar ABBAZ, Amel BENDJEDDOU, Nadia Nait Said, , Djamel BOUCHOUK, Noura Sedira and Soulef Maache, Abdelkrim Gouasmia, Rabah Rehamnia, Mabrouka Dekhici and Didier Villemin},
    journal={Journal of Chemical and Pharmaceutical Research}
    year={2014},
    volume={6},
    number={5},
    pages={1385-1389},
    publisher={}
}