Yoann Aubin, Evelina Colacino, Djamel Bouchouk, Isabelle Chataigner, Maria del Mar Sanchez, Jean Martinez and Georges Dewynter (2012) Unprecedented directed oxidative Cross-Coupling of Sulfahydantoins with aldehydes via a radica Sulfonate-Sulfinate conversion. New J. Chem., 2012, 36, 1560-1563.. New. J. Chem , (),
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Abstract
An unexpected C–C cross-coupling radical oxidation involving
aldehydes and glycine enolate equivalents such as activated
mesyl-sulfahydantoins leading to b,b0-disubstituted aspartate
semialdehydes (ASA) instead of the expected threonine analogues
was observed and various a-substituted non-proteinogenic amino acid
analogues were synthesized. A radical mechanism was envisaged and
supported by DFT calculations.
aldehydes and glycine enolate equivalents such as activated
mesyl-sulfahydantoins leading to b,b0-disubstituted aspartate
semialdehydes (ASA) instead of the expected threonine analogues
was observed and various a-substituted non-proteinogenic amino acid
analogues were synthesized. A radical mechanism was envisaged and
supported by DFT calculations.
Information
| Item Type | Journal |
|---|---|
| Divisions | |
| ePrint ID | 344 |
| Date Deposited | 2015-05-04 |
| Further Information | Google Scholar |
| URI | https://univ-soukahras.dz/en/publication/article/344 |
BibTex
@article{uniusa344,
title={Unprecedented directed oxidative Cross-Coupling of Sulfahydantoins with aldehydes via a radica Sulfonate-Sulfinate conversion. New J. Chem., 2012, 36, 1560-1563.},
author={Yoann Aubin, Evelina Colacino, Djamel Bouchouk, Isabelle Chataigner, Maria del Mar Sanchez, Jean Martinez and Georges Dewynter},
journal={New. J. Chem}
year={2012},
volume={},
number={},
pages={},
publisher={}
}
title={Unprecedented directed oxidative Cross-Coupling of Sulfahydantoins with aldehydes via a radica Sulfonate-Sulfinate conversion. New J. Chem., 2012, 36, 1560-1563.},
author={Yoann Aubin, Evelina Colacino, Djamel Bouchouk, Isabelle Chataigner, Maria del Mar Sanchez, Jean Martinez and Georges Dewynter},
journal={New. J. Chem}
year={2012},
volume={},
number={},
pages={},
publisher={}
}