Department of Material Sciences

https://www.univ-soukahras.dz/en/dept/sm

Lecturer	Mounir AZOUZ
Information	Bachelor - Organic Chemistry Department of Material Sciences Website : https://www.univ-soukahras.dz/en/module/3444 Semester : S5 Unit : UEF5 Credit : 6 Coefficient: 3
Content	.CHEMICAL REACTIVITY 1- Electronic effects. 2- Energy parameters of a reaction. 3- Transition state and reaction intermediates. 4- Approximation of molecular orbitals: Introduction to reaction mechanisms. 5- Ionic reactions. 6- Elimination reactions 7- Electrophilic additions on the C-=C double bond. 8- Oxidation. 9- Carbonyl and organic synthesis. 10-Nucleophilic reactivity of eolisable carbonyl systems. 11- Reactivity of amines and imines. 12- Conjugated carbonyls. II/ MULTIFUNCTIONAL COMPOUNDS 1. Polyenes: methods of preparation, reactivity (Diels-alder and other reaction of cycloaddition). 2. Polyhalogenated compounds: methods of preparation and reactivity. 3. Poly-Hydroxylated Compounds (POLYOLS): Dihydroxylated derivatives (diols): geminal diols (carbonyl hydrates), glycols -glycols or 1,2-diol, -glycols or 1,3-diol, glycols or 1,4-diol)- Triols: glycerol (1,2,3- triol)- Diphenols (catechol, resorcinol, hydroquinone, flavonoids, anthocyanidin, etc.) 4. Polyaldehydes and polyketones: 1.2; 1.3; 1.4: methods of preparation, (condensation aldol, Claisen condensation, Dieckman condensation, Robinson annealing) reactivity and identification by analytical methods. 5. Polyacids and unsaturated acids (aliphatic and aromatic): methods of preparation, reactivity identification by analytical methods. 6. Hydroxy acids and Ketoacids: methods of preparation, reactivity and identification by analytical methods. 7. Multi-Functional Carbonyl Compounds: Unsaturated aldehydes and ketones, ketenes - Ethylene acids- Dicarbonyl compounds (-dicarbonyl, -dicarbonyl and - dicarbonyls, quinones)- Polyacids- Saturated diacids- Unsaturated diacids aliphatics- Aromatic diacids- Keto-acids (-keto acids, - ketones- Hydroxy acids. 8. Multi-functional amines: Aliphatic diamines- Aromatic diamines- aminoalcohols- aminophenols- enamines
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