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Synthesis, Characterization and Electrical Study of New Bis-fused Tetrathiafulvalene Contains Functional Groups

https://www.univ-soukahras.dz/en/publication/article/460

Meriam BOUMEDJOUT, Amel BENDJEDDOU, Tahar ABBAZ, Siham TIAOUIANINE, Lakhmici KABOUB, Abdelkrim GOUASMIA and Didier VILLEMIN (2015) Synthesis, Characterization and Electrical Study of New Bis-fused Tetrathiafulvalene Contains Functional Groups. Oriental journal of chemistry , 31(4), 1887-1895, OJCHEG

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New series of bis-fused tetrathiafulvalene contains functional groups was newly synthesized. The synthesis was carried out by using routes involving cross coupling, reduction,oxidation, and Wittig-type reactions. The identity of these new donors is confirmed by NMR 1 H,mass spectrometry, and elemental analysis. We have used the cyclic voltammetry in order to determine the character donors-π of these molecules and to verify the reversibility of the redox process involved. Molecular orbital diagram has been calculated using density functional calculations. Charge transfer complexes with tetraflurotetracyano-quinodimethane (TCNQF4)wereprepared by chemical redox reactions.

Item Type:	Journal
Divisions:	» Laboratory for Terrestrial and Aquatic Ecosystems » Faculty of Science and Technology
ePrint ID:	460
Date Deposited:	2016-01-02
Further Information:	Google Scholar
URI:	https://www.univ-soukahras.dz/en/publication/article/460